Hi Harshal,
In standard ESS personal data and personal profile you can't acheive. But we have Badi HRPAD00INFTYDB in this you can trigger your workflow so it wont go for the update instead it goes for approval.
If you want to acheive by standard SAP Process,
We have HCM Process and forms in that you can edit infotype and it goes for approval.
Refer to the below link,
SAP Library - HCM Processes and Forms
Regards,
Meera